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Recent ATESR Lab results suggested that aside from being generally more
difficult to collect in an ESP, collection of powdered activated carbon
(PAC) also is substantially different than fly ash.
The analysis uses historical power generation and coal usage data
for the U.S. and assumes that, 1) fine PAC exhibits size and optical
characteristics similar to black carbon (BC, aka soot), and 2) the much
lower resistivity of PAC as compared to fly ash can be parameterized in
terms of in a collection efficiency differential.
The resulting estimates (shown below) present black carbon (BC)
emissions increases from coal-fired power plants during PAC injection as
a function of PAC injection rate and the differential ESP collection
efficiency between PAC and fly ash.
The baseline BC content of fine fly ash emitted from ESPs is not
well characterized and is the source of significant variability in the
estimated BC emissions increases: assuming
high BC content on emitted fine fly ash from ESPs results in lower
estimated increases during PAC injection, with the reverse being true
for assumed low BC content in emitted fine fly ash.
In the case of low BC content of the emitted fine fly ash (top
figure, below), projected increases in BC emissions are measured in
terms of multiples: the lowest
PAC injection rate resulted in > 300% increase in BC emissions even when
applying the overly optimistic assumption of no collection efficiency
differential between PAC and fly ash. In
the case of high BC content of the emitted fine fly ash, increases
ranged from 5 to 73%.
Projections were also developed for both bromine-impregnated and finely
ground sorbents.


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